Chapter 18: 18-18-1P f (page 570)
Name the following ethers:
f)
Short Answer
f) The name of the given ether is allyl vinyl ether.
Chapter 18: 18-18-1P f (page 570)
Name the following ethers:
f)
f) The name of the given ether is allyl vinyl ether.
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Get started for freeThe Zeisel method is an old analytical procedure for determining the number of methoxyl groups in a compound. A weighed amount of the compound is heated with concentrated HI, ether cleavage occurs, and the iodomethane product is distilled off and passed into an alcohol solution of
Aldehydes and ketones undergo acid-catalyzed reaction with alcoholsto yield hemiacetals,compounds that have one alcohol-like oxygenand one ether-like oxygen bonded to the same carbon. Further reactionof a hemiacetal with alcohol then yields an acetal,a compound that hastwo ether-like oxygens bonded to the same carbon.
(a)Show the structures of the hemiacetal and acetal you would obtainby reaction of cyclohexanone with ethanol.
(b)Propose a mechanism for the conversion of a hemiacetal into anacetal.
Name the following ethers:
b)
Safrole, a substance isolated from the oil of sassafras, is used as a perfumery agent. Propose a synthesis of safrole from catechol (1,2-benzenediol).
When 2-methyl-2,5-pentanediol is treated with sulfuric acid, dehydration occurs and 2,2 dimethyltetrahydrofuran is formed. Suggest amechanism for this reaction. Which of the two oxygen atoms is mostlikely to be eliminated, and why?
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