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Name the following ethers:

f)

Short Answer

Expert verified

f) The name of the given ether is allyl vinyl ether.

Step by step solution

01

Nomenclature of ethers

The nomenclature of ether is done by naming the smallest chain with oxygen (alkoxy), and then, at the end longest carbon chain (alkane) is added. For example, methoxyethane is the IUPAC name, and ethyl methyl ether is the common name.

02

The name of the ether

f) In this compound, the smallest carbon chain connected to the oxygen atom is vinyl (โˆ’CH=CH2), and the other group is allyl (CH2=CHCH2โˆ’). Therefore, the name of the ether is Allyl vinyl ether.

Allyl vinyl ether

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Most popular questions from this chapter

The Zeisel method is an old analytical procedure for determining the number of methoxyl groups in a compound. A weighed amount of the compound is heated with concentrated HI, ether cleavage occurs, and the iodomethane product is distilled off and passed into an alcohol solution ofAgNO3 , where it reacts to form a precipitate of silver iodide. The AgI is then collected and weighed, and the percentage of methoxyl groups in the sample is thereby determined. For example, 1.06 g of vanillin, the material responsible for the characteristic odour of vanilla, yields 1.60 g of AgI. If vanillin has a molecular weight of 152, how many methoxyl groups does it contain?

Aldehydes and ketones undergo acid-catalyzed reaction with alcoholsto yield hemiacetals,compounds that have one alcohol-like oxygenand one ether-like oxygen bonded to the same carbon. Further reactionof a hemiacetal with alcohol then yields an acetal,a compound that hastwo ether-like oxygens bonded to the same carbon.

(a)Show the structures of the hemiacetal and acetal you would obtainby reaction of cyclohexanone with ethanol.

(b)Propose a mechanism for the conversion of a hemiacetal into anacetal.

Name the following ethers:

b)

Safrole, a substance isolated from the oil of sassafras, is used as a perfumery agent. Propose a synthesis of safrole from catechol (1,2-benzenediol).

When 2-methyl-2,5-pentanediol is treated with sulfuric acid, dehydration occurs and 2,2 dimethyltetrahydrofuran is formed. Suggest amechanism for this reaction. Which of the two oxygen atoms is mostlikely to be eliminated, and why?

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