Chapter 23: Q28E (page 783)
Based on your answers to Problem 23-27, predict the dehydration product for each reaction and provide the mechanism.
Short Answer
The products are formed by dehydration reaction.
Chapter 23: Q28E (page 783)
Based on your answers to Problem 23-27, predict the dehydration product for each reaction and provide the mechanism.
The products are formed by dehydration reaction.
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Get started for freePredict the addition product for each reaction below and provide the mechanism.
The Stork enamine reaction and the intramolecular aldol reaction can be carried out in sequence to allow the synthesis of cyclohexanones. For example, the reaction of the pyrrolidine enamine of cyclohexanone with 3-buten-2-one, followed by enamine hydrolysis and base treatment, yields the product indicated. Write each step, and show the mechanism of each.
The following molecule was formed by an intramolecular aldol reaction. What dicarbonyl precursor was used for its preparation?
How could you prepare the following cyclohexanones by combining a Stork enamine reaction with an intramolecular aldol condensation? (See Problem 23-64.)
Which of the following compounds can probably be prepared by a mixed aldol reaction? Show the reactants you would use in each case.
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