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Chapter 23: Q23-10P (page 764)

What product would you expect to obtain from the base treatment of

1,6-cyclo-decanedione?

Short Answer

Expert verified

It gives seven-member ring fused with the five-member ring.

Step by step solution

01

Intramolecular aldol condensation:

02

Removal of a water molecule on heating and formation of double bond:

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Most popular questions from this chapter

In contrast to the rapid reaction shown in Problem 23-60, ethyl acetoacetate requires a temperature over 150 °C to undergo the same kind of cleavage reaction. How can you explain the difference in reactivity?

Treatment of a 1,3-diketone such as 2,4-pentanedione with base does not give an aldol condensation product. Explain.

What product would you obtain from a base-catalyzed Michael reaction of 3-buten-2-one with each of the following nucleophilic donors?

What product would you expect from the following mixed Claisen-like reaction?

What enone product would you expect from aldol condensation of each of the following compounds?
See all solutions

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