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Chapter 23: Q10P (page 764)

What product would you expect to obtain from the base treatment of 1,6-cyclo-decanedione?

Short Answer

Expert verified

It gives seven-member ring fused with the five-member ring.

Step by step solution

01

Intramolecular aldol condensation:


02

Removal of a water molecule on heating and formation of double bond:

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Most popular questions from this chapter

The Darzens reaction involves a two-step, base-catalyzed condensation of ethyl chloroacetate with a ketone to yield an epoxy ester. The first step is a carbonyl condensation reaction, and the second step is an SN2 reaction. Write both steps, and show their mechanisms.

Isoleucine, another of the twenty amino acids found in proteins, metabolized by a pathway that includes the following step. Propose a mechanism.

Dieckmann cyclization of diethyl 3-methylheptanedioate gives a mixture of two๐›ƒ-keto ester products. What are their structures, and why is a mixture formed?

Propose a mechanism for the following base-catalyzed isomerization:

Fill in the missing reagents aโ€“h in the following scheme:
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