Chapter 15: Q15-3P (page 455)
Draw structures corresponding to the following IUPAC names:
(a) p-Bromochlorobenzene
(b) p-Bromotoluene
(c) m-Chloroaniline
(d) 1-Chloro-3,5-dimethylbenzene
Chapter 15: Q15-3P (page 455)
Draw structures corresponding to the following IUPAC names:
(a) p-Bromochlorobenzene
(b) p-Bromotoluene
(c) m-Chloroaniline
(d) 1-Chloro-3,5-dimethylbenzene
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Get started for freeThe following molecular model is that of a carbocation. Draw two resonance structures for the carbocation, indicating the positions of the double bonds.
Cyclooctatetraene readily reacts with potassium metal to form the stable cyclooctatetraene dianion, . Why do you suppose this reaction occurs so easily? What geometry do you expect for the cyclooctatetraene dianion?
Draw an orbital picture of furan to show how the molecule is aromatic.
Show the relative energy levels of the seven p molecular orbitals of the cycloheptatrienyl system. Tell which of the seven orbitals are filled in the cation, radical, and anion, and account for the aromaticity of the cycloheptatrienyl cation.
What is the structure of a hydrocarbon that hasin its mass spectrum and has the followingNMR spectrum? 7.25 d (5 H, broad singlet); 2.90 d (1 H, septet, J 5 7 Hz); 1.22 d (6 H, doublet, J 5 7 Hz).
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