Chapter 15: Q 15-15-18 E-d (page 477)
Give IUPAC names for the following compounds
d)
Short Answer
d)
1-bromo-2-propylbenzene
Chapter 15: Q 15-15-18 E-d (page 477)
Give IUPAC names for the following compounds
d)
d)
1-bromo-2-propylbenzene
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Get started for freeCycloheptatrienone is stable, but cyclopentadienone is so reactive that it can’t be isolated. Explain, taking the polarity of the carbonyl group into account.
Cycloheptatrienone Cyclopentadienone
In 1932, A. A. Levine and A. G. Cole studied the ozonolysis of o-xylene and isolated three products: glyoxal, 2,3-butanedione, and pyruvaldehyde:
In what ratio would you expect the three products to be formed if o-xylene is a resonance hybrid of two structures? The actual ratio found was 3 parts glyoxal, 1 part 2,3-butanedione, and 2 parts pyruvaldehyde. What conclusions can you draw about the structure of o-xylene?
Azo dyes are the major source of artificial color in textiles and food. Part of the reason for their intense coloring is the conjugation from an electron-donating group through the diazo bridge to an electron-withdrawing group on the other side. For the azo dyes below, draw a resonance form that shows how the electron-donating group is related to the electron-withdrawing group on the other side of the diazo bridge. Used curved arrows to show how the electrons are reorganized.
a.
Methyl orange
b.
C.I. Acid Red 74
The compound below is the product initially formed in a Claisen rearrangement (Section 18-4). This product is not isolated but tautomerizes to its enol form. Give the structure of the enol and provide an explanation as to why the enol tautomer is favored.
Azulene, a beautiful blue hydrocarbon, is an isomer of naphthalene. Is azulene aromatic? Draw a second resonance form of azulene in addition to that shown.
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