Chapter 15: Q 15-15-18 E-c (page 477)
Give IUPAC names for the following compounds
c)
Short Answer
c)
1-bromo-3,5-dimethylbenzene
Chapter 15: Q 15-15-18 E-c (page 477)
Give IUPAC names for the following compounds
c)
c)
1-bromo-3,5-dimethylbenzene
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Get started for freeThe proton NMR spectrum of a compound with formula is shown. The normal carbon-13 and DEPT experimental results are tabulated. The infrared spectrum shows peaks at 3432 and and a series of medium-sized peaks between 1618 and . Draw the structure of this compound.
The proton NMR spectrum for a compound with formula is shown below. The infrared spectrum has a strong band at . The normal carbon-13 NMR spectral results are tabulated along with the DEPT-135 and DEPT-90 information. Draw the structure of this compound.
Bextra, a COX-2 inhibitor once used in the treatment of arthritis, contains an isoxazole ring. Why is the ring aromatic?
Bextra
Cyclooctatetraene readily reacts with potassium metal to form the stable cyclooctatetraene dianion, . Why do you suppose this reaction occurs so easily? What geometry do you expect for the cyclooctatetraene dianion?
Propose structures for aromatic hydrocarbons that meet the following descriptions:
(a) C9H12; gives only one C9H11Brproduct on substitution of hydrogen on the aromatic ring with bromine
(b)C10 H14; gives only one C10H13Clproduct on substitution of hydrogen on the aromatic ring with chlorine
(c) C8H10; gives three C8H9Brproducts on substitution of hydrogen on the aromatic ring with bromine
(d)C10 H14 ; gives two C10H13Clproducts on substitution of hydrogen on the aromatic ring with chlorine
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