Chapter 7: Q7-25E (page 219)
The following alkyl bromide can be made by HBr addition to three different alkenes. Show their structures.
Chapter 7: Q7-25E (page 219)
The following alkyl bromide can be made by HBr addition to three different alkenes. Show their structures.
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Get started for freeRank the carbocations below in terms of increasing stability:
Which of the following compounds can exist as pairs of cis-trans isomers? Draw each cis-trans pair, and indicate the geometry of each isomer.
What about the second step in the electrophilic addition of HCl to an alkeneโthe reaction of chloride ion with the carbocation intermediate? Is this step exergonic or endergonic? Does the transition state for this second step resemble the reactant (carbocation) or product (alkyl chloride)? Make a rough drawing of what the transition-state structure might look like.
Trans-Cyclooctene is less stable than cis-cyclooctene by 38.5 kJ/mol, but trans-cyclononene is less stable than cis-cyclononene by only 12.2 kJ/mol. Explain.
Which of the following compounds can exist as pairs of cis-trans isomers? Draw each cis-trans pair, and indicate the geometry of each isomer.
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