Chapter 7: Q44E (page 219)
Q 44Draw and name the 17 alkene isomers,C6H12 , including E, Z isomers.
Short Answer
Answer
Chapter 7: Q44E (page 219)
Q 44Draw and name the 17 alkene isomers,C6H12 , including E, Z isomers.
Answer
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Get started for freeVinylcyclopropane reacts with HBr to yield a rearranged alkyl bromide. Follow the flow of electrons as represented by the curved arrows, show the structure of the carbocation intermediate in brackets, and show the structure of the final product.
On treatment with HBr, vinylcyclohexane undergoes addition and rearrangement to yield 1-bromo-1-ethylcyclohexane. Using curved arrows, propose a mechanism to account for this result.
The isobutyl cation spontaneously rearranges to the tert-butyl cation by a hydride shift. Is the rearrangement exergonic or endergonic? Draw what you think the transition state for the hydride shift might look like according to the Hammond postulate.
Name the following alkenes:
Assign stereochemistry (E or Z) to the double bond in the following compound, and convert the drawing into a skeletal structure (red = O):
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