Chapter 17: Q11P (page 543)
Use the reaction of a Grignard reagent with a carbonyl compound to synthesize the following compound:
Short Answer
The reaction of cyclohexanone with Grignard reagent is shown as,
Chapter 17: Q11P (page 543)
Use the reaction of a Grignard reagent with a carbonyl compound to synthesize the following compound:
The reaction of cyclohexanone with Grignard reagent is shown as,
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Get started for freeDraw the structure of the carbonyl compound(s) from which each of the following alcohols might have been prepared, and show the products you would obtain by treatment of each alcohol with (1) Na metal, (2) , and (3) Dess-Martin periodinane.
(a)
(b)
Galactose, a constituent of the disaccharide lactose found in dairy products, is metabolized by a pathway that includes the isomerization of UDP-galactose to UDP-glucose, where UDP = uridylyl diphosphate. The enzyme responsible for the transformation uses as cofactor. Propose a mechanism.
Draw and name the eight isomeric alcohols with the formula C5H12O
What product (s) would you expect from dehydration of the following alcohols with in pyridine? Indicate the major product in each case.
(a)
(b)
(C)
(d)
(e)
What products would you expect to obtain from reaction of 1-methylcyclohexanol with the following reagents?
(a) HBr (b) NaH (c) H2SO4 (d) Na2Cr2O7
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