Chapter 6: Q100P (page 287)
What stereoisomers are obtained when (S)-3-methyl-1-pentene reacts with Cl2?
Short Answer
The formation of the stereoisomer is trans-1,2dichloro-(S)-3-methyl- pentane.
Chapter 6: Q100P (page 287)
What stereoisomers are obtained when (S)-3-methyl-1-pentene reacts with Cl2?
The formation of the stereoisomer is trans-1,2dichloro-(S)-3-methyl- pentane.
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Get started for freea. Identify two alkenes that react with HBr to form 1-bromo-1-methylcyclohexane without undergoing a carbocation rearrangement.
b. Would both alkenes form the same alkyl halide if DBr were used instead of HBr? (D is an isotope of H, so D+ reacts like H+.)
Each of the following reactions has two nucleophiles that could add to the intermediate formed by the reaction of the alkene with an electrophile. What is the major product of each reaction
Which compound is hydrated more rapidly?
Draw the mechanism for the reaction of cyclohexene with HCl
The second-order rate constant (in units of M-1 s-1) for acid-catalysed hydration at 25 ยฐC is given for each of the following alkenes:
a. Calculate the relative rates of hydration of the alkenes. (Hint: Divide each rate constant by the smallest rate constant of the series: 3.51 ร 10-8.)
b. Why does (Z)-2-butene react faster than (E)-2-butene?
c. Why does 2-methyl-2-butene react faster than (Z)-2-butene?
d. Why does 2,3-dimethyl-2-butene react faster than 2-methyl-2-butene?
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