Chapter 23: Q33P (page 1097)
Question: Do all triacylglycerols have the same number of asymmetric centers?
Short Answer
Different kinds of triacylglycerols have different number of asymmetric centers.
Chapter 23: Q33P (page 1097)
Question: Do all triacylglycerols have the same number of asymmetric centers?
Different kinds of triacylglycerols have different number of asymmetric centers.
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Get started for freereduces unsaturated thioesters to saturated thioesters. The reaction is thought to take place by a mechanism that involves radicals. Propose a mechanism for this reaction.
Propose a mechanism for the -elimination reaction shown on page 1082.
The enzyme that catalyzes the bond cleavage reaction that converts serine to glycine removes the substituent (R) bonded to the \(\alpha \)-carbon in the first step of the reaction. Starting with PLP bound to serine in an imine linkage, propose a mechanism for this reaction. (Hint:The first step involves removal of the proton from serineโs OH group.)
Question: For each of the following reactions, name both the enzyme that catalyzes the reaction and the required coenzyme:
Explain why the ability of PLP to catalyze an amino acid transformation is greatly reduced if a PLP- requiring enzymatic reaction is carried out at a pH at which the pyridine nitrogen is not protonated.
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