Chapter 1: Q57P (page 2)
Rank the bonds from the most polar to least polar.
a. C - O,C - F,C - N
b. C - Cl > C - Br > C - I
c. H - O,H - N,H - C
d. C - H,C - C,C - N
Short Answer
a. C-F>C-O>C-N
b. C-Cl>C-Br>C-I
c. H-O>H-N>H-C
d. C-N>C-H>C-C
Chapter 1: Q57P (page 2)
Rank the bonds from the most polar to least polar.
a. C - O,C - F,C - N
b. C - Cl > C - Br > C - I
c. H - O,H - N,H - C
d. C - H,C - C,C - N
a. C-F>C-O>C-N
b. C-Cl>C-Br>C-I
c. H-O>H-N>H-C
d. C-N>C-H>C-C
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Excess ammonia must be used when a primary amine is synthesized by reductive amination. What product will be obtained if the reaction is carried out with excess carbonyl compound?
Describe the orbital used in bonding and the bond angles in the following compounds:
a. CH3O-
b. CO2
c. H2CO
d. N2
e. BF3
An atom with a formal charge does not necessarily have more or less electron density than the atoms in the molecule without formal charges. We can see this by examining the potential maps for H20,H3O+ and HO-.
a. What are the relative bond lengths and strengths of the bonds in Cl2 and Br2 ?
b. What are the relative lengths and strengths of carbon-halogen bonds in CH3F,CH3Cl and CH3Br ?
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