Chapter 1: Q22P (page 19)
Change the following condensed structure to Kekulẻ structures:
a. CH3NH(CH2)2CH3
b.(CH3)2CHCl
c.(CH3)3CBr
d.(CH3)3C(CH2)3CHO
Chapter 1: Q22P (page 19)
Change the following condensed structure to Kekulẻ structures:
a. CH3NH(CH2)2CH3
b.(CH3)2CHCl
c.(CH3)3CBr
d.(CH3)3C(CH2)3CHO
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Get started for freeWhat orbitals are used to form 10 sigma bonds in propane( CH 3CH 2CH3)?
A tertiary amine reacts with hydrogen peroxide to form a tertiary amine oxide.
Tertiary amine oxides undergo a reaction similar to the Hofmann elimination reaction (Section 10.10), called a Cope elimination. In this reaction, a tertiary amine oxide, rather than a quaternary ammonium ion, undergoes elimination. A strong base is not needed for a Cope elimination because the amine oxide acts as its own base.
Does the Cope elimination have an alkene-like transition state or a carbanion-like transition state?
Draw the following orbitals:
a. 3sorbital
b. 4sorbitalc.
c. 3porbital
Imines can exist as stereoisomers. The isomers are named using the E, Z system of nomenclature (Section 4.2). The lone pair has the lowest priority.
Draw the structure of each of the following compounds:
a. the (E)-hydrazone of benzaldehyde
b. the (Z)-oxime of propiophenone
A ketone can be prepared from the reaction of a nitrile with a Grignard reagent. Describe the intermediate formed in this reaction, and show how it can be converted to a ketone.
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