Chapter 15: Q79P (page 736)
Identify the major and minor products of the following reaction:
Chapter 15: Q79P (page 736)
Identify the major and minor products of the following reaction:
All the tools & learning materials you need for study success - in one app.
Get started for freeProblem:What acyl chloride and amine are required to synthesize the following amides?
a. N-ethylbutanamide b. N,N-dimethylbenzamide
Write the mechanism for the acid-catalyzed reaction of an amide with an alcohol to form an ester.
The reaction of a nitrile with an alcohol in the presence of a strong acid forms an N-substituted amide. This reaction, known as the Ritter reaction, does not work with primary alcohols.
a. Propose a mechanism for the Ritter reaction.
b. Why does the Ritter reaction not work with primary alcohols?
c. How does the Ritter reaction differ from the acid-catalyzed hydrolysis of a nitrile to form an amide?
Primary amines can also be prepared by the reaction of an alkyl halide with azide ion, followed by catalytic hydrogenation. What advantage do this method and the Gabriel synthesis have over the synthesis of a primary amine using an alkyl halide and ammonia?
a. If the equilibrium constant for the reaction of acetic acid and ethanol to form ethyl acetate is 4.02, what is the concentration of ethyl acetate at equilibrium if the reaction is carried out with equal amounts of acetic acid and ethanol?
b. What is the concentration of ethyl acetate at equilibrium if the reaction is carried out with 10 times more ethanol than acetic acid? Hint: Recall the quadratic equation: ax2+ b + c = 0
c. What is the concentration of ethyl acetate at equilibrium if the reaction is carried out with 100 times more ethanol than acetic acid?
What do you think about this solution?
We value your feedback to improve our textbook solutions.