Chapter 17: Q28P (page 825)
Draw the products of the following reactions:
Short Answer
The product followed as:
Chapter 17: Q28P (page 825)
Draw the products of the following reactions:
The product followed as:
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Get started for freeWhich of the following compounds decarboxylates when heated?
Explain why a racemic mixture is formed when (R)-2-methylpentanal is dissolved in an acidic or basic solution.
Compound A with molecular formula C6H10 has two peaks in its 1H NMR spectrum, both of which are singlets (with ratio 9 : 1). Compound Areacts
with an acidic aqueous solution containing mercuric sulfate to form compound B,which gives a positive iodoform test (Problem 58) and has an 1H NMR
spectrum that shows two singlets (with ratio 3 : 1). Identify A and B.
An aldol addition can be catalyzed by acids as well as by bases. Propose a mechanism for the acid-catalyzedaldol addition of propanal.
If the preference for formation of a six-membered ring were not so great, what other cyclic product would be formed from the intramolecular aldol addition of
a.2,6-heptanedione? b. 2,8-nonanedione?
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