Chapter 17: Q 6 TP (page 857)
Do a retrosynthetic analysis on each of the following compounds, ending with the given starting materials:
(a)
(b)
Short Answer
Answer:
(a)
(b)
Chapter 17: Q 6 TP (page 857)
Do a retrosynthetic analysis on each of the following compounds, ending with the given starting materials:
(a)
(b)
Answer:
(a)
(b)
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a. an ether? b. an aldehyde? c. an alkene? d. an amine?
Orsellinic acid, a common constituent of lichens, is synthesized from the condensation of acetyl thioester and malonyl thioester. If a lichen is grown on amedium containing acetate that was radioactively labeled with 14C at the carbonyl carbon, which carbons will be labelled in orsellinic acid?
Show how the following compounds can be synthesized. The only carbon-containing compounds available to you for each synthesis are shown.
When a dilute solution of acetaldehyde in D2O containing NaOD is shaken, explain why the methyl hydrogens are exchanged with deuterium but the hydrogen attached to the carbonyl carbon is not.
Draw the product of the reaction of each of the following compounds with a base:
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