Chapter 4: Q94P (page 185)
For each of the following structures, draw the most stable chair conformer.
Short Answer
We have to draw the most stable chair conformer:
a)
b)
Chapter 4: Q94P (page 185)
For each of the following structures, draw the most stable chair conformer.
We have to draw the most stable chair conformer:
a)
b)
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Get started for freeNaproxen, a nonsteroidal anti-inflammatory drug that is the active ingredient in Aleve (p. 115), has a specific rotation of +66. One commercial preparation result in a mixture with a 97% enantiomeric excess.
a. Does naproxen have the R or the S configuration?
b. What percent of each enantiomer is obtained from the commercial preparation?
Assign relative priorities to each set of substituents:
a. -CH2CH2CH3 -CH(CH3)2 -CH=CH2 -CH3
b. -CH2NH2 -NH2 -OH -CH2OH
c. -C(=O)CH3 -CH=CH2 -Cl -CโกN
Draw the stereoisomers of the following amino acids. Indicate pairs of enantiomers and pairs of diastereomers.
a. Stereoisomers with two asymmetric centres are called ___ if the configuration of both asymmetric centers in one stereoisomer is the opposite of the configuration of the asymmetric centers in the other stereoisomer.
b. Stereoisomers with two asymmetric centers are called ___ if the configuration of both asymmetric centers in one stereoisomer is the same as the configuration of the asymmetric centers in the other stereoisomer.
c. Stereoisomers with two asymmetric centers are called ___ if one of the asymmetric centers has the same configuration in both stereoisomers and the other asymmetric center has the opposite configuration in the two stereoisomers.
Explain why the enantiomers of 1,2-dimethylaziridine can be separated even though one of the โgroupsโ attached to nitrogen is a lone pair.
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