Chapter 8: Q28P (page 318)
What are the products of the following reactions, assuming that one equivalent of each reagent is used in each reaction?
Chapter 8: Q28P (page 318)
What are the products of the following reactions, assuming that one equivalent of each reagent is used in each reaction?
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Which carbocation in each pair is more stable?
b. CH3OC+H2 or CH3NHC+H2
a. The following compounds have the same molecular formula as benzene. How many monosubstituted products would each have?
1.HCโกCCโกCCH2CH3 2. CH2โกCHCโกCCHโกCH2
b. How many disubstituted products would each of the preceding compounds have? (Do not include stereoisomers.)
c. How many disubstituted products would each of the compounds have if stereoisomers are included?
Answer the following questions for the molecular orbitals (MOs) of 1,3,5,7-octatetraene:
a. How many MOs does the compound have?
b. Which are the bonding MOs, and which are the antibonding MOs?
c. Which MOs are symmetric, and which are antisymmetric?
d. Which MO is the HOMO and which is the LUMO in the ground state?
e. Which MO is the HOMO and which is the LUMO in the excited state?
f. What is the relationship between HOMO and LUMO and symmetric and antisymmetric orbitals?
g. How many nodes does the highest-energy MO of 1,3,5,7-octatetraene have between the nuclei?
What is the major product obtained from the addition of hbr to the following compound.
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