Chapter 22: Q29P (page 1060)
Which of the following two compounds eliminates HBr more rapidly in a basic solution?
Short Answer
The answer is,
Chapter 22: Q29P (page 1060)
Which of the following two compounds eliminates HBr more rapidly in a basic solution?
The answer is,
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3-Amino-2-oxindole catalyzes the decarboxylation of -keto acids.
a. Propose a mechanism for the catalyzed reaction.
b. Would 3-aminoindole be equally effective as a catalyst?
The deuterium kinetic isotope effect for the hydrolysis of aspirin is 2.2. What does this tell you about the kind of catalysis exerted by the o- carboxyl substituent?
Which of the following amino acid side chains can form an imine with a substrate?
The rate constant for the uncatalyzed reaction of two molecules of glycine ethyl ester to form glycylglycine ethyl ester is 0.6M-1S-1 . in the presence of \(C{o^{2 + }}\), the rate constant is \(1.5 \times 1{0^{\bf{6}}}{M^{ - 1}}{s^{ - 1}}\). What rate enhancement does the catalyst provide?
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