Chapter 3: Q61 P (page 137)
Draw a skeletal structure for an alkane that has
a. six carbons, all secondary.
b. eight carbons and only primary hydrogens.
c. seven carbons with two isopropyl groups.
Short Answer
a.
b.
c.
Chapter 3: Q61 P (page 137)
Draw a skeletal structure for an alkane that has
a. six carbons, all secondary.
b. eight carbons and only primary hydrogens.
c. seven carbons with two isopropyl groups.
a.
b.
c.
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Get started for freeUsing the data obtained in Problem 85, calculate the amount of steric strain in each of the chair conformers of 1,1,3-trimethylcyclohexane. Which conformer predominates at equilibrium?
a. Draw a potential energy diagram for rotation about the C-C bond of 1,2-dichloroethane through 360degree, starting with the least stable conformer. The anti-conformer is 1.2 kcal/mol more stable than a gauche conformer. A gauche conformer has two energy barriers, 5.2 kcal/mol and 9.3 kcal/mol.
b. Draw the conformer that is present in greatest concentration.
c. How much more stable is the most stable staggered conformer than the most stable eclipsed conformer?
d. How much more stable is the most stable staggered conformer than the least stable eclipsed conformer?
Are the following compounds primary, secondary, or tertiary?
Rank the following compounds from highest boiling to lowest boiling:
In which solvent would cyclohexane have the lowest solubility: 1-pentanol, diethyl ether, ethanol, or hexane?
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