Chapter 3: Q58 P (page 137)
Which of the following represents a cis isomer?
Short Answer
Compounds C and D represent cis isomers.
Chapter 3: Q58 P (page 137)
Which of the following represents a cis isomer?
Compounds C and D represent cis isomers.
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Get started for freea. Draw Newman projections of the two conformers of cis-1,3-dimethylcyclohexane.
b. Which of the conformers predominates at equilibrium?
c. Draw Newman projections of the two conformers of the trans isomer.
d. Which of the conformers predominates at equilibrium?
One of the chair conformers of cis-1,3-dimethylcyclohexane is 5.4 kcal/mol less stable than the other. How much steric strain does a 1,3-diaxial interaction between two methyl groups introduce into the conformer?
Using Newman projections, draw the most stable conformer for each of the following:
a. 3-methylpentane, viewed along the C-2 - C-3bond
b. 3-methylhexane, viewed along the C-3 - C-4bond
c. 3,3-dimethylhexane, viewed along the C-3 - C-4bond
Draw skeletal structures for the following:
a. 5-ethyl-2-methyloctane
b. 1,3-dimethylcyclohexane
c. 2,3,3,4-tetramethylheptane
d. propyl cyclopentane
e. 2-methyl-4-(1-methylethyl) octane
f. 2,6-dimethyl-4-(2-methylpropyl)decane
Ansaid and Motrin belong to the group of drugs known as nonsteroidal anti-inflammatory drugs (NSAIDs). Both are only slightly soluble in water, but one is a little more soluble than the other. Which of the drugs has the greater solubility in water?
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