Chapter 5: Q7TP (page 190)
Draw curved arrows to show the movement of the electrons that result in formation of the given product(s).
Chapter 5: Q7TP (page 190)
Draw curved arrows to show the movement of the electrons that result in formation of the given product(s).
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Get started for freeSqualene, a hydrocarbon with the molecular formula C30H50, is obtained from shark liver. (Squalus is Latin for “shark.”) If squalene is an acyclic compound, how many π bonds does it have?
Question: Draw the structure for each of the following:
a. 3,3-dimethylcyclopentene
b. 6-bromo-2,3-dimethyl-2-hexene
c. ethyl vinyl ether
d. allyl alcohol
Question: Which of the following are electrophiles, and which are nucleophiles?
Which is more stable?
Question: a. Which of the monosubstituted cyclohexanes in Table 3.9 on p. 128 has a negative ∆G° for the conversion of an axial-substituted chair conformer to an equatorial-substituted chair conformer?
b.Which monosubstituted cyclohexane has the most negative ∆G° for this conversion?
c. Which monosubstituted cyclohexane has the greatest preference for an equatorial position?
d. Calculate ∆G° for the conversion of “axial” methylcyclohexane to “equatorial” methylcyclohexane at 25 °C.
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