Chapter 5: Q17P (page 201)
Question: Draw the products that would be obtained by following the incorrect arrows in the box entitled “A Few Words about Curved Arrows” and explain what is wrong with the structures you obtain
Chapter 5: Q17P (page 201)
Question: Draw the products that would be obtained by following the incorrect arrows in the box entitled “A Few Words about Curved Arrows” and explain what is wrong with the structures you obtain
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Get started for freeWhat is the molecular formula for each of the following?
a. For a reaction with ∆H° = -12 kcal/mol and ∆S° = 0.01kcal mol-1 K-1, calculate the ∆G° and the equilibrium constant at: 1. 30 °C and 2. 150 °C.
b. How does ∆G° change as T increases?
c. How does Keq change as T increases?
How many of the following names are correct? Correct the incorrect names.
a. 3-pentene
b. 2-octene
c. 2-vinylpentane
d. 1-ethyl-1-pentene
e. 5-ethylcyclohexene
f. 5-chloro-3-hexene
g. 2-ethyl-2-butene
h. (E)-2-methyl-1-hexene
i. 2-methylcyclopentene
a. Which of the following reactions will have the larger ΔS° value?
b. Will the ΔS° value be positive or negative?\
Question: a. Which of the monosubstituted cyclohexanes in Table 3.9 on p. 128 has a negative ∆G° for the conversion of an axial-substituted chair conformer to an equatorial-substituted chair conformer?
b.Which monosubstituted cyclohexane has the most negative ∆G° for this conversion?
c. Which monosubstituted cyclohexane has the greatest preference for an equatorial position?
d. Calculate ∆G° for the conversion of “axial” methylcyclohexane to “equatorial” methylcyclohexane at 25 °C.
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