Chapter 5: Q14P (page 197)
Question: Identify the nucleophile and the electrophile in the following acid–base reactions:
Short Answer
AlCl3is an electrophileand NH3 is a nucleophile.
The H+ of HBr is the electrophile and OH- is the nucleophile.
Chapter 5: Q14P (page 197)
Question: Identify the nucleophile and the electrophile in the following acid–base reactions:
AlCl3is an electrophileand NH3 is a nucleophile.
The H+ of HBr is the electrophile and OH- is the nucleophile.
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Get started for freea. What is the equilibrium constant for a reaction that is carried out at 25°C (298 K) with ΔH° = 20 kcal/mol and ΔS° = 5.0 x 10-2 kcal mol-1 K-1?
b. What is the equilibrium constant for the same reaction carried out at 125°C?
From the following rate constants, determined at five temperatures, calculate the experimental energy of activation and ΔG±,ΔH±,andΔS±for the reaction at 30°C:
In a reaction in which reactant A is in equilibrium with product B at
25 °C, what relative amounts of A and B are present at equilibrium if ΔG° at 25 °C is
a. 2.72 kcal/mol?
b. 0.65 kcal/mol?
c. -2.72 kcal/mol?
d. -0.65 kcal/mol?
Draw the Skeletal structure for each of the following:
a. (Z)-1,3,5-tribromo-2-pentene
b. (Z)-3-methyl-2-heptene
c. (E)-1,2-dibromo-3-isopropyl-2-hexene
d. vinyl bromide
e. 1,2-dimethylcyclopentene
f. diallyl amine
Draw curved arrows to show the movement of the electrons that result in formation of the given product(s).
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