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Question: Draw Lewis structures for the following free radicals.

(a)The ethyl radical, CH3-CH2

(b)The tert butyl radical, (CH3 )3C

(c)The isopropyl radical,(2-propyl radical)

(d)The iodine atom

Short Answer

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Answer

Lewis structure ofThe ethyl radical, CH3-CH2

(b)

Lewis structure ofThe tert butyl radical, (CH3 )3C

(c)

Lewis structure ofThe isopropyl radical,(2-propyl radical)

(d)

Lewis structure ofThe iodine atom

Step by step solution

01

Lewis structures

The formation of covalent bondsin molecules is shown in an easier way by Lewis structures.The valence electrons are represented by dots in the Lewis structure, and one bond is represented as two electrons. In drawing Lewis structures, the atoms are arranged so that all of them have eight valence electrons. The exception is hydrogen, which can have a maximum of two valence electrons.

02

Free radicals

An atom or group of atoms containing odd or unpaired electrons is known as the free radical. Free radicals are electrically neutral. They are highly reactive species formed by homolytic fission of a covalent bond.

03

 Step 2: Drawing Lewis structures of the given free radicals

(a) A carbon atom has valence electrons, and a hydrogen atom has valence electron.

Lewis structure ofethyl radical, CH3-CH2

(b) A carbon atom has valence electrons, and a hydrogen atom has valence electron.

Lewis structure oftert butyl radical, (CH3 )3C

(c) A carbon atom has valence electrons, and a hydrogen atom has valence electron.

Lewis structure ofisopropyl radical,(2-propyl radical)

(d) An iodine atom has valence electrons.

Lewis structure ofiodine atom

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Most popular questions from this chapter

(a) Draw a reaction-energy diagram for the following reaction:

The activation energy is 4 kJ/mol (1 kcal/mol), and the overall for the reaction is -110 kJ/mol (-27 kcal/mol).

(b) Give the equation for the reverse reaction.

(c) What is the activation energy for the reverse reaction?

When a small amount of iodine is added to a mixture of chlorine and methane, it prevents chlorination from occurring. Therefore, iodine is a free-radical inhibitor for this reaction. Calculateฮ”H0values for the possible reactions of iodine with species present in the chlorination of methane and use these values to explain why iodine inhibits the reaction. (The I-Clbond-dissociation enthalpy is 211 kJ/molor 50 kcal/mol).

Propionitrile()is deprotonated by very strong bases. Write resonance forms to show the stabilization of the carbanion that results.

Treatment oftert - butyl alcohol with concentrated HBrgives tert butyl bromide.

When the concentration of H+is doubled, the reaction rate doubles. When the concentration of tert- butyl alcohol is tripled, the reaction rate triples. When the bromide ion concentration is quadrupled, however, the reaction rate is unchanged. Write the rate equation for this reaction.

The following reaction has a value ofฮ”G0=โ€‰-2.1โ€‰kJ/molโ€‰โ€‰(-0.50โ€‰โ€‰kcal/mol)

CH3Brโ€‰โ€‰+โ€‰โ€‰H2Sโ€‰โ€‰โ‡„โ€‰โ€‰CH3SHโ€‰โ€‰+โ€‰โ€‰HBr

(a) Calculate Keqat room temperature(250C) for this reaction as written.

(b)Starting with a1M solution of CH3Brand H2S, calculate the final concentrations of all four species at equilibrium.

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