Chapter 3: Q14P (page 165)
Draw a perspective representation of the most stable conformation of 3-methylhexane.
Short Answer
The most stable conformation of 3-methylhexane is;
Chapter 3: Q14P (page 165)
Draw a perspective representation of the most stable conformation of 3-methylhexane.
The most stable conformation of 3-methylhexane is;
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Get started for freeConstruct a graph, similar to Figure 3-11, of the torsional energy of along the.Placein front, represented by three bonds coming together in a Y shape, andin back, represented by a circle with three bonds pointing out from it. Define the dihedral angle as the angle between the methyl group on the front carbon and ethyl group on the back carbon. Begin your graph at thedihedral angle and begin to turn the front carbon. Show the Newman projection and the approximate energy at eachof rotation. Indicate which conformations are the most stable (lowest energy) and the least stable (highest energy).
Draw the two chair conformations of each compound, and label the substituents as axial and equatorial. In each case, determine which conformation is more stable.
(a)
(b)
(c)
(d)
(e)
(f)
Question: Draw a graph, similar to Figure 3-9, of the torsional strain of as it rotates about the bond between and . Show the dihedral angle and draw a Newman projection for each staggered and eclipsed conformation.
trans - 1,2 - dimethylcyclobutane is more stable than cis - 1,2 -dimethylcyclobutane, but cis - 1,3 - dimethylcyclobutane is more stable than trans - 1,3 - dimethylcyclobutane. Use drawings to explain these observations.
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