Warning: foreach() argument must be of type array|object, bool given in /var/www/html/web/app/themes/studypress-core-theme/template-parts/header/mobile-offcanvas.php on line 20

Draw a perspective representation of the most stable conformation of 3-methylhexane.

Short Answer

Expert verified

The most stable conformation of 3-methylhexane is;

Step by step solution

01

The Conformation.

The conformation is a process of rotating the compound about the sigma bonds to get a different conformational isomer.

02

The skeletal conformer of 3-methylhexane converted to Newman projection.

The given compound consists of 7 carbon atoms, out of which; one carbon atom (methyl group) is attached to the 3rd carbon of the hexane chain.

In the flying wedge projectionof the given compound; the 3rd and 4th carbon are brought in front of each other.

There is one H-atom in 3rd carbon and two H-atoms on 4th carbon.

03

The most stable conformation of 3-methylhexane.

This is the anti-conformation of 3-methylhexane in Newman Projection;

Here, the two bulky ethyl groups are at anti-position and one methyl is in gauche interaction with one of the ethyl groups; making it the most stable conformer.

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with Vaia!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

Construct a graph, similar to Figure 3-11, of the torsional energy of 3-methylpentanealong theC2โˆ’C3.PlaceC2in front, represented by three bonds coming together in a Y shape, andC3in back, represented by a circle with three bonds pointing out from it. Define the dihedral angle as the angle between the methyl group on the front carbon and ethyl group on the back carbon. Begin your graph at 00thedihedral angle and begin to turn the front carbon. Show the Newman projection and the approximate energy at each600of rotation. Indicate which conformations are the most stable (lowest energy) and the least stable (highest energy).

Draw the two chair conformations of each compound, and label the substituents as axial and equatorial. In each case, determine which conformation is more stable.

(a)cis-1-ethyl-2-isopropylcyclohexane

(b)trans-1-ethyl-2-isopropylcyclohexane

(c)cis-1-ethyl-3-methylcyclohexane

(d)trans-1-ethyl-3-methylcyclohexane

(e)cis-1-ethyl-4-methylcyclohexane

(f)trans-1-ethyl-4-methylcyclohexane

Question: Draw a graph, similar to Figure 3-9, of the torsional strain of 2-methylpropane as it rotates about the bond between and . Show the dihedral angle and draw a Newman projection for each staggered and eclipsed conformation.

trans - 1,2 - dimethylcyclobutane is more stable than cis - 1,2 -dimethylcyclobutane, but cis - 1,3 - dimethylcyclobutane is more stable than trans - 1,3 - dimethylcyclobutane. Use drawings to explain these observations.

  1. There are 18 isomeric alkanes of molecular formula C8H18. Draw and name any eight of them.
  2. Draw and name the six isomeric cyclopentane of molecular formula C7H14. These will include four constitutional isomers, of which two show geometric (cis-trans) stereoisomerism.
See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.

Sign-up for free