Chapter 3: Q11P (page 160)
Draw Newman projections of the following molecules viewed from the direction of the arrows.
(a)
(b)
(c)
Short Answer
(a)
(b)
(c)
Chapter 3: Q11P (page 160)
Draw Newman projections of the following molecules viewed from the direction of the arrows.
(a)
(b)
(c)
(a)
(b)
(c)
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Get started for freeThe cyclohexane chair shown in Figure 3-22 has the headrest to the right and the footrest to the left. Draw a cyclohexane chair with its axial and equatorial bonds, showing the headrest to the left and the footrest to the right.
In each pair of compounds, which compound has the higher boiling point? Explain your reasoning.
(a) Nonane or 3-methylheptane
(b) Octane or 2,3,4-trimethylpentane
(c) 2,3,5-trimethylhexane or nonane
Draw the two chair conformations of each compound, and label the substituents as axial and equatorial. In each case, determine which conformation is more stable.
(a)
(b)
(c)
(d)
(e)
(f)
Using what you know about the conformational energetics of substituted cyclohexanes, predict which of the two isomers is more stable. Explain your reasoning.
List each set of compounds in order of increasing boiling point.
(a) hexane, octane, and decane
(b) octane, (CH3)3C-C(CH3)3, and CH3CH2C(CH3)2CH2CH2CH3
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