Chapter 25: Q1P. (page 1303)
Question: Trimyristin, a solid fat present in nutmeg, is hydrolyzed to give one equivalent of glyceroland three equivalents of myristic acid. Give the structure of trimyristin.
Chapter 25: Q1P. (page 1303)
Question: Trimyristin, a solid fat present in nutmeg, is hydrolyzed to give one equivalent of glyceroland three equivalents of myristic acid. Give the structure of trimyristin.
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Get started for freeOils containing highly unsaturated acids like linolenic acid undergo oxidation in air. This reaction, called oxidative rancidity, is accelerated by heat, explaining why saturated fats are preferred for deep fat frying.
(a) Molecular oxygen is a diradical. What type of mechanism does a diradical suggest for this reaction?
(b) Why is the position shown (carbon-11) a likely site for attack?
(c) Propose a plausible mechanism for this reaction.
(d) BHA and BHT are antioxidants added to foods to interrupt the oxidation mechanism. Suggest how these molecules might work as antioxidants.
Which of the following chemical reactions could be used to distinguish between a polyunsaturated animal oil and a synthetic cooking oil containing a mixture of saturated and unsaturated hydrocarbons? Explain your reasoning.
The synthesis of the alkylbenzenesulfonate detergent shown in figure 25-6 begins with the partial polymerization of propylene to give a pentamer.
Show how aromatic substitution reactions can convert this pentamer to the final synthetic detergent.
Give the general classification of each compound.
The following five compounds are found in Vicks Vapo-Rubยฎ.
(a) Which are terpenes? Circle the isoprene units of the terpenes.
(b) Do you expect Vicks Vapo-Rup to be optically active ? Explain.
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