Chapter 18: Q11P (page 912)
Show how you would accomplish the following synthetic conversions. You may use any additional reagents and solvents you need.
Chapter 18: Q11P (page 912)
Show how you would accomplish the following synthetic conversions. You may use any additional reagents and solvents you need.
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Get started for freeName the following ketones and aldehydes. When possible, give both a common name and an IUPAC name.
(j) (k) (l)
Show how you would accomplish the following synthesis.
(a) Acetphenoneโ acetophenone cyanohydrin
(b) Cyclopentancarbaldehydeโ 2-cyclopentyl-2-hydroxyacetic acid
(c) Hexan-1-ol โ2-hydroxyheptanoic acid
One of these reacts with dilute aqueous acid and the other does not. Give a mechanism for the one that reacts and show why this mechanism does not work for the other one.
Within each set of structures, indicate which will react fastest, and which slowest, toward nucleophilic addition in basic conditions.
(a)
(b)
(c)
Show how the following transformations may be accomplished in good yield. You may use any additional reagents that are needed.
(a) bromobenzene โ propiophenone
(b) CH3CH2CN โ heptan-3-one
(c) benzoic acid โ phenyl cyclopentyl ketone
(d) 1-bromo-hept-2-ene โ oct-3- enal
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