Chapter 19: Q24P (page 1014)
Propose a mechanism for the synthesis of methyl orange.
Short Answer
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Chapter 19: Q24P (page 1014)
Propose a mechanism for the synthesis of methyl orange.
Step 1:
Step 2:
Step 3:
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Get started for freeShow how to prepare the following aromatic amines by aromatic nitration, followed by reduction. You may use benzene and toluene as your aromatic starting materials.
Which of the amines listed next is resolved into enantiomers? In each case, explain why interconversion of the enantiomers does or does not take place.
(a)Cis-2-methylcyclohexanamine
(b) N-ethyl-N-methylcyclohexanamine
(c) N-methylaziridine
(d) Ethylmethylanilinium iodide
(e) Methylethylpropylisopropylammonium iodide
Question. Propose a mechanism for the sulfonation of pyridine, and point out why sulfonation occurs at 3-position.
Show how you would accomplish the following synthetic conversions.
(a) benzyl bromide to benzylamine
(b) 1-bromo-2-phenylethane to 3-phenylpropan-1-amine
(c) pentanoic acid to pentan-1-amine
(d) pentanoic acid to hexan-1-amine
(e) (R)-2-bromobutane to (S)-butan-2-amine
(f) (R)-2-bromobutane to (S)-2-methylbutan-1-amine
(g) hexan-2-one to 1-amino-2-methylhexan-2-ol
Propose a mechanism for nitration of pyridine at the 4-position, and show why this orientation is not observed.
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