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Write structural formulas for the following compounds (includes both old- and new-style names).

(a) 2-octyne (b) ethyl isopentyl acetylene (c) ethynylbenzene

(d) cyclohexyl acetylene (e) 5-methyl-3-octyne (f) trans-3,5-dibromocyclodecyne

(g) 5,5-dibromo-4-phenylcyclooct-1-yne (h) (E)-6-ethyloct-2-en-4-yne

(i) 1,4-heptadiyne (j) vinylacetylene (k) (S)-3-methyl-1-penten-4-yne

Short Answer

Expert verified

The structural formula is the complete form of showing how the molecules in the compound are presented.

Structure formula is the complete representation of any chemical compound, and it is much more complex than condensed formula.

Step by step solution

01

Step 1: Structural formula:

The structural formula is the complete form of showing how the molecules in the compound are presented.

Structure formula is the complete representation of any chemical compound, and it is much more complex than condensed formula.

02

Writing structural formula of the given compound:

(a) The structural formula of 2-octyne is:

(b) The structural formula of ethyl isopentyl acetylene is:

(c) The structural formula of ethynylbenzene is:

(d) The structural formula of cyclohexyl acetylene is:

(e) The structural formula of 5-methyl-3-octyne is:

(f) The structural formula of trans-3,5-dibromocyclodecyne is:

(g) The structural formula of 5,5-dibromo-4-phenylcyclooct-1-yne is:

(h) Structure formula of (E)-6-ethyloct-2-en-4-yne is:

(i) The structural formula of 1,4-heptadiyne is:

(j) The Structural formula of vinylacetylene is:

(k) The Structural formula of (S)-3-methyl-1-penten-4-yne is:

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Most popular questions from this chapter

Question: Show how you might synthesize the following compounds, using acetylene and any suitable alkyl halides as your starting materials. If the compound given cannot be synthesized by this method, explain why. (a) hex-1-yne (b) hex-2-yne (c) hex-3-yne (d) 4-methylhex-2-yne (e) 5-methylhex-2-yne (f) cyclodecyne.

Question:Using hex-1-ene as your starting material, show how you would synthesize the following compounds. (Once you have shown how to synthesize a compound, you may use it as the starting material in any later parts of this problem)

(a)1,2-dibromohexane

(b)hex-1-yne

(c)2,2-dibromohexane

(d)hex-2-yne

(e)hexan-2-one

(f)hexanal

(g)pentanoic acid

(h)pentanal

(i)undec-6-yn-5-ol

Oxidative cleavages can help to determine the positions of the triple bonds in alkynes.

(a) An unknown alkyne undergoes oxidative cleavage to give adipic acid and two equivalents of acetic acid. Propose a structure for the alkyne.

(b) An unknown alkyne undergoes oxidative cleavage to give the following triacid plus one equivalent of propionic acid. Propose a structure for the alkyne.

Question: Show how you would synthesize each compound, beginning with acetylene and any necessary additional reagents.

(a) prop-2-yn-1-ol (propargyl alcohol)

(b) hept-2-yn-4-ol

(c) 2-phenylbut-3-yn-2-ol

(d) 3-methylhex-4-yn-3-ol

Question:When treated with hydrogen and a platinum catalyst, an unknown compound X absorbs 5 equivalents of hydrogen to give n-butylcyclohexane. Treatment of X with an excess of ozone, followed by dimethyl sulfide and water, gives the following products:

Propose a structure for the unknown compound X. Is there any uncertainty in your structure?

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