Chapter 6: 46P-b (page 330)
Question: Using cyclohexane as one of your starting materials, show how you would synthesize the following compounds.
b)
Short Answer
b) The synthesis reaction of given compound is as follows,
Chapter 6: 46P-b (page 330)
Question: Using cyclohexane as one of your starting materials, show how you would synthesize the following compounds.
b)
b) The synthesis reaction of given compound is as follows,
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Get started for freePropose an SN1 mechanism for the solvolysis of 3-bromo-2,3-dimethylpentane in ethanol.
Predict the compound in each pair that will undergo the SN2 reaction faster.
(a.)
(b.)
(c.)
(d.)
(e.)
(f.)
For each pair of compounds, predict which one has the higher molecular dipole moment, and explain your reasoning.
(a) ethyl chloride or ethyl iodide
(b) 1-bromopropane or cyclopropane
(c) cis-2,3-dibromobut-2-ene or trans-2,3-dibromobut-2-ene
(d) cis-1,2-dichlorocyclobutane or trans-1,3-dichlorocyclobutane.
Triethyloxonium tetrafluoroborate, (CH3CH2)3O+ BF4โ, is a solid with melting point 91โ92ยฐC. Show how this reagent can transfer an ethyl group to a nucleophile (Nuc:โ) in an SN2 reaction. What is the leaving group? Why might this reagent be preferred to using an ethyl halide? (Consult Table 6-2.)
(b)In contrast, optically active butan-2-ol does not racemize on treatment with a solution of KOH. Explain why a reaction like that in part (a) does not occur.
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