Chapter 6: Problem 44
Show how to convert ethylene to these compounds. (a) Ethane (b) Ethanol (c) Bromoethane (d) 2-Chloroethanol (e) 1,2 -Dibromoethane (f) 1,2 -Ethanediol (g) Chloroethane
Chapter 6: Problem 44
Show how to convert ethylene to these compounds. (a) Ethane (b) Ethanol (c) Bromoethane (d) 2-Chloroethanol (e) 1,2 -Dibromoethane (f) 1,2 -Ethanediol (g) Chloroethane
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Get started for freePredict the organic product(s) of the reaction of 2 -butene with each reagent. (a) \(\mathrm{H}_{2} \mathrm{O}\left(\mathrm{H}_{2} \mathrm{SO}_{4}\right)\) (b) \(\mathrm{Br}_{2}\) (c) \(\mathrm{Cl}_{2}\) (d) \(\mathrm{Br}_{2}\) in \(\mathrm{H}_{2} \mathrm{O}\) (e) \(\mathrm{HI}^{2}\) (f) \(\mathrm{Cl}_{2}^{2}\) in \(\mathrm{H}_{2} \mathrm{O}\) (g) \(\mathrm{Hg}(\mathrm{OAc})_{2}, \mathrm{H}_{2} \mathrm{O}\) (h) product (g) \(+\mathrm{NaBH}_{4}\)
Reaction of \(\alpha\)-pinene with borane followed by treatment of the resulting trialkylborane with alkaline hydrogen peroxide gives the following alcohol. Of the four possible cis,trans isomers, one is formed in over \(85 \%\) yield. (a) Draw structural formulas for the four possible cis,trans isomers of the bicyclic alcohol. (b) Which is the structure of the isomer formed in \(85 \%\) yield? How do you account for its formation? Create a model to help you make this prediction.
Using the BDE values from Appendix 3, calculate the \(\Delta H_{\text {rxn }}^{0}\) value and state if the reaction below is exothermic or endothermic.
Draw a structural formula for the cycloalkene with the molecular formula
\(\mathrm{C}_{6} \mathrm{H}_{10}\) that reacts with \(\mathrm{Cl}_{2}\) to give
each compound.
(a)
Account for the fact that treating propenoic acid (acrylic acid) with HCl gives only 3-chloropropanoic acid.
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