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Following are structural formulas and common names for four molecules that contain both a carbon-carbon double bond and another functional group. Give each an IUPAC name.

Short Answer

Expert verified
Answer: The IUPAC name of CH3CH2CH(CH3)CHO is 3-Methylbutanal.

Step by step solution

01

Identify the longest carbon chain containing the highest priority functional group

In this molecule, the longest carbon chain has 4 carbon atoms: CH3CH2CH(CH3)CHO. The functional group present in this molecule is an aldehyde (CHO) which has higher priority over the carbon-carbon double bond.
02

Number the carbon atoms

We will number the carbon atoms in the chain starting from the end at which the aldehyde group is present, assigning it the lowest possible number. The numbering of the carbon atoms will be: 1 -CHO 2 3 4 -CH3
03

Name the substituents and their positions on the carbon chain

There is a methyl (CH3) group attached to the third carbon atom in the chain. Therefore, it is called 3-methyl.
04

Assemble the IUPAC name for the molecule

Now, we can assemble the IUPAC name for the molecule, using the substituents' names and the positions. The name will be: 3-Methylbutanal

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Most popular questions from this chapter

Draw structural formulas for these alkenes. (a) trans-2-Methyl-3-hexene (b) 2 -Methyl-2-hexene (c) 2-Methyl-1-butene (d) 3 -Ethyl-3-methyl-1-pentene (e) 2,3-Dimethyl-2-butene (f) cis-2-Pentene (g) (Z)-1-Chloropropene (h) 3-Methylcyclohexene (i) 1-Isopropyl-4-methylcyclohexene (j) (E) -2,6-Dimethyl-2,6-octadiene (k) 3-Cyclopropyl-1-propene (1) Cyclopropylethene (m) 2-Chloropropene (n) Tetrachloroethylene (o) 1-Chlorocyclohexene

Draw the structural formula for at least one bromoalkene with the molecular formula \(\mathrm{C}_{5} \mathrm{H}_{9} \mathrm{Br}\) that shows: (a) Neither \(E, Z\) isomerism nor chirality. (b) \(E, Z\) isomerism but not chirality. (c) Chirality but not \(E_{1} Z\) isomerism. (d) Both chirality and \(E, Z\) isomerism.

\(\beta\)-Ocimene, a triene found in the fragrance of cotton blossoms and several essential oils, has the IUPAC name \((Z)-3,7\)-dimethyl- \(1,3,6\)-octatriene. Draw a structural formula for \(\beta\)-ocimene.

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Nepetalactone is the active ingredient of catnip. It is isolated as an oil from the plant Nepata cataria. Show that it is a terpene (i.e., that its carbon skeleton can be divided into isoprene units). Is the molecule chiral? How many stereoisomers are possible?

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