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Will carbon dioxide be evolved when sodium bicarbonate is added to an aqueous solution of each compound? Explain. (a) Sulfuric acid (b) Ethanol (c) Ammonium chloride

Short Answer

Expert verified
Answer: Carbon dioxide will evolve when sodium bicarbonate is added to aqueous solutions of sulfuric acid and ammonium chloride, but not when added to the ethanol solution.

Step by step solution

01

Write the chemical formulas

First, we need to write the chemical formulas for the reactants and products in the reactions. (a) Sodium bicarbonate + Sulfuric acid NaHCO3 + H2SO4 (b) Sodium bicarbonate + Ethanol NaHCO3 + C2H5OH (c) Sodium bicarbonate + Ammonium chloride NaHCO3 + NH4Cl
02

Identify and balance the chemical reactions

Now we need to identify the possible reactions between sodium bicarbonate and each compound. We will do this by combining the reactants to form products and then balance the resulting chemical equations. (a) Sodium bicarbonate + Sulfuric acid NaHCO3 + H2SO4 -> Na2SO4 + H2O + CO2 Balanced equation: NaHCO3 + H2SO4 -> Na2SO4 + H2O + CO2 (b) Sodium bicarbonate + Ethanol In this case, no reaction occurs between sodium bicarbonate and ethanol, as ethanol is a weak acid and cannot donate a proton to react with the bicarbonate ion. Hence, carbon dioxide will not evolve in this reaction. (c) Sodium bicarbonate + Ammonium chloride NaHCO3 + NH4Cl -> NaCl + NH3 + CO2 + H2O Balanced equation: NaHCO3 + NH4Cl -> NaCl + NH3 + CO2 + H2O
03

Determine the evolution of carbon dioxide

Finally, we need to check if CO2 is being released in any of the reactions (a) Sodium bicarbonate + Sulfuric acid Balanced equation: NaHCO3 + H2SO4 -> Na2SO4 + H2O + CO2 The reaction produces CO2, so carbon dioxide will evolve when sodium bicarbonate is added to an aqueous solution of sulfuric acid. (b) Sodium bicarbonate + Ethanol No reaction occurs between sodium bicarbonate and ethanol; hence, carbon dioxide will not evolve in this case. (c) Sodium bicarbonate + Ammonium chloride Balanced equation: NaHCO3 + NH4Cl -> NaCl + NH3 + CO2 + H2O The reaction produces CO2, so carbon dioxide will evolve when sodium bicarbonate is added to an aqueous solution of ammonium chloride. In conclusion, carbon dioxide will evolve when sodium bicarbonate is added to aqueous solutions of sulfuric acid and ammonium chloride but not when it's added to the ethanol solution.

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Most popular questions from this chapter

Methyl isocyanate, \(\mathrm{CH}_{3}-\mathrm{N}=\mathrm{C}=\mathrm{O}\), is used in the industrial synthesis of a type of pesticide and herbicide known as a carbamate. As a historical note, an industrial accident in Bhopal, India, in 1984 resulted in leakage of an unknown quantity of this chemical into the air. An estimated 200,000 people were exposed to its vapors, and over 2000 of these people died. (a) Write a Lewis structure for methyl isocyanate and predict its bond angles. What is the hybridization of its carbonyl carbon? Of its nitrogen atom? (b) Methyl isocyanate reacts with strong acids, such as sulfuric acid, to form a cation. Will this molecule undergo protonation more readily on its oxygen or nitrogen atom? In considering contributing structures to each hybrid, do not consider structures in which more than one atom has an incomplete octet.

Each molecule or ion can function as a base. Write a structural formula of the conjugate acid formed by reaction of each with \(\mathrm{HCl}\). (a) \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}\) (b) \(\mathrm{HCH}\) (c) \(\left(\mathrm{CH}_{3}\right)_{2} \mathrm{NH}\) (d) \(\mathrm{HCO}_{3}^{-}\)

Write equations for the reaction of each compound with $\mathrm{H}_{2} \mathrm{SO}_{4}$, strong protic acid. (a) \(\mathrm{CH}_{3} \mathrm{OCH}_{3}\) (b) \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{SCH}_{2} \mathrm{CH}_{3}\) (c) \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{NHCH}_{2} \mathrm{CH}_{3}\) (d) \(\mathrm{CH}_{3} \mathrm{NCH}_{3}\) (e) \(\mathrm{CH}_{3}{ }_{\mathrm{C} C H}^{3}\)

Write an equation for the acid-base reaction between 2,4-pentanedione and sodium ethoxide and calculate its equilibrium constant, \(K_{\mathrm{eq}}\). The \(\mathrm{p} K_{\mathrm{a}}\) of 2,4 -pentanedione is 9 ; that of ethanol is \(15.9\).

Sodium hydride, \(\mathrm{NaH}\), is available commercially as a gray-white powder. It melts at \(800^{\circ} \mathrm{C}\) with decomposition. It reacts explosively with water and ignites spontaneously upon standing in moist air. (a) Write a Lewis structure for the hydride ion and for sodium hydride. Is your Lewis structure consistent with the fact that this compound is a high- melting solid? Explain. (b) When sodium hydride is added very slowly to water, it dissolves with the evolution of a gas. The resulting solution is basic to litmus. What is the gas evolved? Why has the solution become basic? (c) Write an equation for the reaction between sodium hydride and 1-butyne, \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{C} \equiv \mathrm{CH}\). Use curved arrows to show the flow of electrons in this reaction.

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