Chapter 4: Problem 25
Will carbon dioxide be evolved when sodium bicarbonate is added to an aqueous solution of each compound? Explain. (a) Sulfuric acid (b) Ethanol (c) Ammonium chloride
Chapter 4: Problem 25
Will carbon dioxide be evolved when sodium bicarbonate is added to an aqueous solution of each compound? Explain. (a) Sulfuric acid (b) Ethanol (c) Ammonium chloride
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Get started for freeMethyl isocyanate, \(\mathrm{CH}_{3}-\mathrm{N}=\mathrm{C}=\mathrm{O}\), is used in the industrial synthesis of a type of pesticide and herbicide known as a carbamate. As a historical note, an industrial accident in Bhopal, India, in 1984 resulted in leakage of an unknown quantity of this chemical into the air. An estimated 200,000 people were exposed to its vapors, and over 2000 of these people died. (a) Write a Lewis structure for methyl isocyanate and predict its bond angles. What is the hybridization of its carbonyl carbon? Of its nitrogen atom? (b) Methyl isocyanate reacts with strong acids, such as sulfuric acid, to form a cation. Will this molecule undergo protonation more readily on its oxygen or nitrogen atom? In considering contributing structures to each hybrid, do not consider structures in which more than one atom has an incomplete octet.
Each molecule or ion can function as a base. Write a structural formula of the conjugate acid formed by reaction of each with \(\mathrm{HCl}\). (a) \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}\) (b) \(\mathrm{HCH}\) (c) \(\left(\mathrm{CH}_{3}\right)_{2} \mathrm{NH}\) (d) \(\mathrm{HCO}_{3}^{-}\)
Write equations for the reaction of each compound with $\mathrm{H}_{2} \mathrm{SO}_{4}$, strong protic acid. (a) \(\mathrm{CH}_{3} \mathrm{OCH}_{3}\) (b) \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{SCH}_{2} \mathrm{CH}_{3}\) (c) \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{NHCH}_{2} \mathrm{CH}_{3}\) (d) \(\mathrm{CH}_{3} \mathrm{NCH}_{3}\) (e) \(\mathrm{CH}_{3}{ }_{\mathrm{C} C H}^{3}\)
Write an equation for the acid-base reaction between 2,4-pentanedione and sodium ethoxide and calculate its equilibrium constant, \(K_{\mathrm{eq}}\). The \(\mathrm{p} K_{\mathrm{a}}\) of 2,4 -pentanedione is 9 ; that of ethanol is \(15.9\).
Sodium hydride, \(\mathrm{NaH}\), is available commercially as a gray-white powder. It melts at \(800^{\circ} \mathrm{C}\) with decomposition. It reacts explosively with water and ignites spontaneously upon standing in moist air. (a) Write a Lewis structure for the hydride ion and for sodium hydride. Is your Lewis structure consistent with the fact that this compound is a high- melting solid? Explain. (b) When sodium hydride is added very slowly to water, it dissolves with the evolution of a gas. The resulting solution is basic to litmus. What is the gas evolved? Why has the solution become basic? (c) Write an equation for the reaction between sodium hydride and 1-butyne, \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{C} \equiv \mathrm{CH}\). Use curved arrows to show the flow of electrons in this reaction.
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