Chapter 26: Problem 9
What is meant by the term hardening as applied to vegetable oils?
Chapter 26: Problem 9
What is meant by the term hardening as applied to vegetable oils?
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How does the presence of unsaturated fatty acids contribute to the fluidity of biological membranes?
Palmitic acid (hexadecanoic acid) is the source of the hexadecyl (cetyl) group in the following compounds. Each is a mild surface-acting germicide and fungicide and is used as a topical antiseptic and disinfectant. They are examples of quaternary ammonium detergents, commonly called "quats." (a) Cetylpyridinium chloride is prepared by treating pyridine with 1 -chlorohexadecane (cetyl chloride). Show how to convert palmitic acid to cetyl chloride. (b) Benzylcetyldimethylammonium chloride is prepared by treating benzyl chloride with \(N\), \(N\)-dimethyl-1-hexadecanamine. Show how this tertiary amine can be prepared from palmitic acid.
Lipases are enzymes that catalyze the hydrolysis of esters, especially esters of glycerol. Because enzymes are chiral catalysts, they catalyze the hydrolysis of only one enantiomer of a racemic mixture. For example, porcine pancreatic lipase catalyzes the hydrolysis of only one enantiomer of the following racemic epoxyester. Calculate the number of grams of epoxyalcohol that can be obtained from \(100 \mathrm{~g}\) of racemic epoxyester by this method.
Explain why coconut oil is a liquid triglyceride even though most of its fatty acid components are saturated.
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