Chapter 25: Problem 40
What is the difference in structure between oligo- and polysaccharides?
Chapter 25: Problem 40
What is the difference in structure between oligo- and polysaccharides?
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Get started for freeDraw a structural formula for the \(\beta\) - \(N\)-glycoside formed between 2 -deoxyD-ribofuranose and adenine.
Draw a Haworth projection and a chair conformation for methyl \(\alpha\)-Dmannopyranoside (methyl \(\alpha\)-D-mannoside). Label the anomeric carbon and the glycosidic bond.
Propose structural formulas for the following polysaccharides. (a) Alginic acid, isolated from seaweed, is used as a thickening agent in ice cream and other foods. Alginic acid is a polymer of D-mannuronic acid in the pyranose form joined by \(\beta-1,4\)-glycosidic bonds. (b) Pectic acid is the main component of pectin, which is responsible for the formation of jellies from fruits and berries. Pectic acid is a polymer of D-galacturonic acid in the pyranose form joined by \(\alpha-1,4\)-glycosidic bonds.
Vanillin (4-hydroxy-3-methoxybenzaldehyde), the principal component of vanilla, occurs in vanilla beans and other natural sources as a \(\beta\)-D-glucopyranoside. Draw a structural formula for this glycoside, showing the D-glucose unit as a chair conformation.
What is the difference in meaning between the terms glycosidic bond and glucosidic bond?
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