Chapter 25: Problem 18
What is the anomeric carbon in a 2-ketohexose?
Chapter 25: Problem 18
What is the anomeric carbon in a 2-ketohexose?
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Get started for freeThe anticlotting property of heparin is partly the result of the negative charges it carries. (a) Identify the functional groups that provide the negative charges. (b) Which type of heparin is a better anticoagulant, one with a high or a low degree of polymerization?
Draw a Haworth projection and a chair conformation for methyl \(\alpha\)-Dmannopyranoside (methyl \(\alpha\)-D-mannoside). Label the anomeric carbon and the glycosidic bond.
Draw chair conformations for \(\alpha\)-D-mannopyranose and \(\beta\)-D-mannopyranose. Label the anomeric carbon in each.
Trehalose is found in young mushrooms and is the chief carbohydrate in the blood of certain insects. Trehalose is a disaccharide consisting of two D-monosaccharide units, each joined to the other by an \(\alpha-1,1\)-glycosidic bond.
Following is a chair conformation for the repeating disaccharide unit in chondroitin 6-sulfate. This biopolymer acts as the flexible connecting matrix between the tough protein filaments in cartilage. It is available as a dietary supplement, often combined with D-glucosamine sulfate. Some believe this combination can strengthen and improve joint flexibility. (a) From which two monosaccharide units is the repeating disaccharide unit of chondroitin 6-sulfate derived? (b) Describe the glycosidic bond between the two units.
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