Chapter 25: Problem 17
Define the terms (a) pyranose and (b) furanose.
Chapter 25: Problem 17
Define the terms (a) pyranose and (b) furanose.
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Get started for freeAn important technique for establishing relative configurations among isomeric aldoses and ketoses is to convert both terminal carbon atoms to the same functional group. This can be done either by selective oxidation or reduction. As a specific example, nitric acid oxidation of D-erythrose gives meso- tartaric acid (Section 3.4B). Similar oxidation of D-threose gives \((2 S, 3 S)\)-tartaric acid. Given this information and the fact that D-erythrose and D-threose are diastereomers, draw Fischer projections for D-erythrose and D-threose. Check your answers against Table 25.1.
Are \(\alpha\)-D-glucose and \(\beta\)-D-glucose enantiomers? Explain.
Convert each chair conformation to an open-chain form and then to a Fischer projection. Name the monosaccharide you have drawn.
How many chiral centers are present in D-glucose? in D-ribose?
Explain the meaning of the designations D and L used to specify the configuration of monosaccharides.
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