Chapter 25: Problem 12
Write Fischer projections for L-ribose and L-arabinose.
Chapter 25: Problem 12
Write Fischer projections for L-ribose and L-arabinose.
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Get started for freePropose structural formulas for the following polysaccharides. (a) Alginic acid, isolated from seaweed, is used as a thickening agent in ice cream and other foods. Alginic acid is a polymer of D-mannuronic acid in the pyranose form joined by \(\beta-1,4\)-glycosidic bonds. (b) Pectic acid is the main component of pectin, which is responsible for the formation of jellies from fruits and berries. Pectic acid is a polymer of D-galacturonic acid in the pyranose form joined by \(\alpha-1,4\)-glycosidic bonds.
What is the meaning of the prefix deoxy- as it is used in carbohydrate chemistry?
Draw a chair conformation for the \(\alpha\) form of a disaccharide in which two units of D-glucopyranose are joined by a \(\beta-1,3\)-glycosidic bond.
Draw chair conformations for \(\alpha\)-D-mannopyranose and \(\beta\)-D-mannopyranose. Label the anomeric carbon in each.
Draw Fischer projections for the product(s) formed by reaction of D-galactose with the following. In addition, state whether each product is optically active or inactive. (a) \(\mathrm{NaBH}_{4}\) in \(\mathrm{H}_{2} \mathrm{O}\) (d) \(\mathrm{Br}_{2} / \mathrm{H}_{2} \mathrm{O} / \mathrm{CaCO}_{3}\) (b) \(\mathrm{H}_{2} / \mathrm{Pt}\) (c) \(\mathrm{HNO}_{y}\), warm (f) \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{NH}_{2}\)
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