Chapter 2: Problem 61
Following are structural formulas for 1,4 -dioxane and piperidine. 1,4-Dioxane is a widely used solvent for organic compounds. Piperidine is found in small amounts in black pepper (Piper nigrum).
Chapter 2: Problem 61
Following are structural formulas for 1,4 -dioxane and piperidine. 1,4-Dioxane is a widely used solvent for organic compounds. Piperidine is found in small amounts in black pepper (Piper nigrum).
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Get started for freeDraw line-angle formulas for the three constitutional isomers with the molecular formula \(\mathrm{C}_{5} \mathrm{H}_{12}\).
Draw the alternative chair conformations for the cis and trans isomers of 1,2 -dimethylcyclohexane, 1,3-dimethylcyclohexane, and 1,4-dimethylcyclohexane. (a) Indicate by a label whether each methyl group is axial or equatorial. (b) For which isomer(s) are the alternative chair conformations of equal stability? (c) For which isomer(s) is one chair conformation more stable than the other?
Indicate whether the compounds in each set are constitutional isomers.
(a) \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}\) and \(\mathrm{CH}_{3}
\mathrm{OCH}_{3}\)
Using a planar pentagon representation for the cyclopentane ring, draw structural formulas for the cis and trans isomers of the following. (a) 1,2 -Dimethylcyclopentane (b) 1,3 -Dimethylcyclopentane
Do the condensed formulas in each pair represent the same compound or
constitutional isomers?
(a) \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{2}
\mathrm{CH}_{2} \mathrm{CH}_{3}\) and
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