Chapter 2: Problem 54
What generalization can you make about the densities of alkanes relative to the density of water?
Chapter 2: Problem 54
What generalization can you make about the densities of alkanes relative to the density of water?
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Get started for freeDraw structural formulas for all of the following. (a) Alcohols with the molecular formula \(\mathrm{C}_{4} \mathrm{H}_{10} \mathrm{O}\) (b) Aldehydes with the molecular formula \(\mathrm{C}_{4} \mathrm{H}_{8} \mathrm{O}\) (c) Ketones with the molecular formula \(\mathrm{C}_{5} \mathrm{H}_{10} \mathrm{O}\) (d) Carboxylic acids with the molecular formula \(\mathrm{C}_{5} \mathrm{H}_{10} \mathrm{O}_{2}\)
Consider 1-bromo-2-methylpropane and draw the following. (a) The staggered conformation(s) of lowest energy (b) The staggered conformation(s) of highest energy
Which cycloalkanes show cis, trans isomerism? For each that does, draw both isomers.
\(1,2,3,4,5,6\)-Hexachlorocyclohexane shows cis,trans isomerism. At one time, a crude mixture of these isomers was sold as an insecticide. The insecticidal properties of the mixture arise from one isomer, known as lindane, which is cis-1,2,4,5-trans3,6-hexachlorocyclohexane. (a) Draw a structural formula for \(1,2,3,4,5,6\)-hexachlorocyclohexane disregarding, for the moment, the existence of cis, trans isomerism. What is the molecular formula of this compound? (b) Using a planar hexagon representation for the cyclohexane ring, draw a structural formula for lindane. (c) Draw a chair conformation for lindane and label which chlorine atoms are axial and which are equatorial. (d) Draw the alternative chair conformation of lindane and again label which chlorine atoms are axial and which are equatorial. (e) Which of the alternative chair conformations of lindane is more stable? Explain.
Write molecular formulas for each bicycloalkane, given its number of carbon atoms. (a) Hydrindane ( 9 carbons) (b) Decalin (10 carbons) (c) Norbornane (7 carbons)
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