Chapter 1: Problem 21
Identify the atom that has each ground-state electron configuration. (a) \(1 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{4}\) (b) \(1 s^{2} 2 s^{2} 2 p^{4}\)
Chapter 1: Problem 21
Identify the atom that has each ground-state electron configuration. (a) \(1 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{4}\) (b) \(1 s^{2} 2 s^{2} 2 p^{4}\)
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Get started for freeAre the structures in each set valid contributing structures? a. b. c. d.
Following is a structural formula of the prescription drug famotidine, marketed by McNeil Consumer Pharmaceuticals Co. under the name Pepcid. The primary clinical use of Pepcid is for the treatment of active duodenal ulcers and benign gastric ulcers. Pepcid is a competitive inhibitor of histamine \(\mathrm{H}_{2}\) receptors that reduces both gastric acid concentration and the volume of gastric secretions. (a) Complete the Lewis structure of famotidine showing all valence electrons and any formal positive or negative charges. (b) Describe each circled bond in terms of the overlap of atomic orbitals.
Draw the delocalized molecular orbitals for the following molecule. Are both \(\pi\) bonds of the triple bond involved in the delocalized orbitals? $$ \mathrm{CH}_{3}-\mathrm{C} \equiv \mathrm{C}-\mathrm{CH}=\mathrm{CH}_{2} $$
(a) Draw a Lewis structure for the ozone molecule, \(\mathrm{O}_{3}\). (The order of atom attachment is \(\mathrm{O}-\mathrm{O}-\mathrm{O}\), and they do not form a ring.) Chemists use ozone to cleave carbon-carbon double bonds (Section 6.5C). (b) Draw four contributing resonance structures; include formal charges. (c) How does the resonance model account for the fact that the length of each \(\mathrm{O}-\mathrm{O}\) bond in ozone \((128 \mathrm{pm})\) is shorter than the \(\mathrm{O}-\mathrm{O}\) single bond in hydrogen peroxide \((\mathrm{HOOH}\), \(147 \mathrm{pm}\) ) but longer than the \(\mathrm{O}-\mathrm{O}\) double bond in the oxygen molecule ( \(123 \mathrm{pm})\) ?
Draw Lewis structures for these functional groups. Show all valence electrons on each. (a) Carbonyl group (b) Carboxyl group (c) Hydroxyl group (d) Ester group (e) Amide group
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