Chapter 2: Problem 33
How many different staggered conformations are there for 2 -methylpropane? How many different eclipsed conformations are there?
Chapter 2: Problem 33
How many different staggered conformations are there for 2 -methylpropane? How many different eclipsed conformations are there?
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Draw the alternative chair conformations for the cis and trans isomers of 1,2 -dimethylcyclohexane, 1,3 -dimethylcyclohexane, and 1,4 -dimethylcyclohexane. (a) Indicate by a label whether each methyl group is axial or equatorial. (b) For which isomer(s) are the alternative chair conformations of equal stability? (c) For which isomer(s) is one chair conformation more stable than the other?
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Draw structural formulas for the cis and trans isomers of hydrindane. Show each ring in its most stable conformation. Which of these isomers is more stable?
Torsional strain resulting from eclipsed \(\mathrm{C}-\mathrm{H}\) bonds is approximately \(4.2 \mathrm{~kJ}\) (1.0 \(\mathrm{kcal}) / \mathrm{mol}\), and that for eclipsed \(\mathrm{C}-\mathrm{H}\) and \(\mathrm{C}-\mathrm{CH}_{3}\) bonds is approximately \(6.3 \mathrm{~kJ}\) \((1.5 \mathrm{kcal}) / \mathrm{mol}\). Given this information, sketch a graph of energy versus dihedral angle for propane.
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