Chapter 6: Problem 6.4 (page 221)
Use curved arrows to show the movement of electrons in each equation.
a.
b.
Short Answer
Answer
a.

b.
Chapter 6: Problem 6.4 (page 221)
Use curved arrows to show the movement of electrons in each equation.
a.
b.
Answer
a.
b.
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Get started for freeWhich bond in each pair has the higher bond dissociation energy?
a.
b.
a. Which corresponds to a negative value of localid="1648198317845" , localid="1648198334107" or Keq= 0.001 ?
b. Which corresponds to a lower value oflocalid="1648198364090" , localid="1648198396853" or localid="1648198411007" ?
Draw an energy diagram for a two-step reaction, , where the relative energy of these compounds is , and the conversion of is rate-determining.
The use of curved arrows is a powerful tool that illustrates even complex reactions.
a. Add curved arrows to show how carbocation A is converted to carbocation B. Label each new bond formed. Similar reactions have been used in elegant synthesis of steroids.
b. Draw the product by following the curved arrows. This reaction is an example of a [3,3] sigma tropic rearrangement, as we will learn in chapter 27.
Consider the following energy diagram for the conversion of .
a. Which points on the graph correspond to transition states?
b. Which points on the graph correspond to reactive intermediates?
c. How many steps are present in the reaction mechanism?
d. Label each step of the mechanism as endothermic or exothermic.
e. Label the overall reaction as endothermic or exothermic.
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