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Chapter 6: Problem 6.32 (page 241)

(a) Draw in the curved arrows to show how A is converted to B in Step [1]. (b) Identify X, using the curved arrows drawn for Step [2].

Short Answer

Expert verified

Answer

(a)

Conversion of A to B

(b)

Conversion of B to X

Step by step solution

01

Step-by-Step SolutionStep 1: Proton Transfer reaction

In acid-base reactions, the base shares its electron density with the most acidic hydrogen atom of the acid. Thus, a proton from the acid is transferred to the base. This step in the acid-base reaction is called the proton transfer step.

02

Addition reaction

When two elements and/or compounds combine to form a new compound, the reaction is called an addition reaction.

03

Determining the products of the given reaction

The curved arrows to show the conversion of A to B are shown hereunder:

Conversion of A to B

As is indicated by the curved arrows, the Bromide anion is added to the ring. One of the two bonds of oxygen with the ring breaks off. The new compound thus formed is 1-bromide-2-hydroxylcyclohexane.

Conversion of B to X

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Most popular questions from this chapter

Rank the indicated bonds in order of increasing bond dissociation energy.

For each rate equation, what effect does the indicated concentration change have on the overall rate of the reaction?

[1] $rate = k [{CH}_{3} {CH}_{2} Br] [^{-} OH]$

tripling the concentration of ${CH}_{3} {CH}_{2} Br$ only
tripling the concentration of – OH only
tripling the concentration of both ${CH}_{3} {CH}_{2} Br$ and – OH

[2]role="math" localid="1648280223497" $rate = k [{({CH}_{3})}_{3} COH]$

doubling the concentration of ${({CH}_{3})}_{3} COH$
increasing the concentration of ${({CH}_{3})}_{3} COH$ by a factor of 10

PGF2α (Section 4.15) is synthesized in cells using a cyclooxygenase enzyme that catalyzesa multistep radical pathway. Two steps in the pathway are depicted in the accompanying equations.

(a) Draw in curved arrows to illustrate how C is converted to D in Step [1].

(b) Identify Y, the product of Step [2], using the curved arrows that are drawn on compound D.

For a reaction with ${ΔH}^{°} = 40 kJ / mol$ , decide which of the following statements is (are) true. Correct any false statement to make it true. (a) ${ΔG}^{°}$ The reaction is exothermic; (b) for the reaction is positive; (c) $K_{eq}$ is greater than 1; (d) the bonds in the starting materials are stronger than the bonds in the product; and (e) the product is favored at equilibrium.

Question: Draw an energy diagram for a reaction in which the products are higher in energy than the starting materials and $E_{a}$ is large. Clearly label all of the following on the diagram: the axes, the starting materials, the products, the transition state, $∆ H^{°}$ ,and $E_{a}$ .

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