Chapter 6: Problem 6.29 (page 241)
Use full-headed or half-headed curved arrows to show the movement of electrons in each reaction.
a.
b.
c.
d.
Short Answer
Answer
a.
b.
c.
d.
Chapter 6: Problem 6.29 (page 241)
Use full-headed or half-headed curved arrows to show the movement of electrons in each reaction.
a.
b.
c.
d.
Answer
a.
b.
c.
d.
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Get started for freea. Which corresponds to a negative value of localid="1648198317845" , localid="1648198334107" or Keq= 0.001 ?
b. Which corresponds to a lower value oflocalid="1648198364090" , localid="1648198396853" or localid="1648198411007" ?
(a) Add curved arrows for each step to show how A is converted to the epoxy ketone C. (b) Classify the conversion of A to C as a substitution, elimination, or addition. (c) Draw one additional resonance structure for B.
Label each statement as true or false. Correct any false statement to make it true.
a. Increasing temperature increases reaction rate.
b. If a reaction is fast, it has a large rate constant.
c. A fast reaction has a large negative value.
d. When is large, the rate constant k is also large.
e. Fast reactions have equilibrium constants > 1.
f. Increasing the concentration of a reactant always increases the rate of a reaction.
Given each of the following values, is the starting material or product favored at equilibrium?
a.
b.
Which value (if any) corresponds to a faster reaction: (a) or ; (b) a reaction temperature of or a reaction temperature of ; (c) or ; (d) role="math" localid="1648275832528" or ?
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