Chapter 6: Problem 6.28 (page 241)
Classify each transformation as substitution, elimination, or addition.
a.
b.
Short Answer
Answer
- Elimination reaction
- Addition reaction
Chapter 6: Problem 6.28 (page 241)
Classify each transformation as substitution, elimination, or addition.
a.
b.
Answer
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Get started for freeThe conversion of acetyl chloride to methyl acetate occurs via the following two-step mechanism:
a. Add curved arrows to show the movement of the electrons in each step.
b. Write the rate equation for this reaction, assuming the first step is rate-determining.
c. If the concentration of were increased 10 times, what would happen to the rate of the reaction?
d. If the concentrations of both and were increased 10 times, what would happen to the rate of the reaction?
e. Classify the conversion of acetyl chloride to methyl acetate as an addition, elimination, or substitution.
For which of the following reactions is a positive value?
a.
b.
What carbon radical is formed by homolysis of the bond in propylbenzene? Draw all reasonable resonance structures for this radical.
What carbon radical is formed by homolysis of therole="math" localid="1648540916945" bond in propylbenzene? Draw all reasonable resonance structures for this radical.
The bond dissociation energy of one of the C-H bonds is considerably less than the bond dissociation energy of the other. Which C-H bond is weaker? Offer an explanation.
Label each statement as true or false. Correct any false statement to make it true.
a. Increasing temperature increases reaction rate.
b. If a reaction is fast, it has a large rate constant.
c. A fast reaction has a large negative value.
d. When is large, the rate constant k is also large.
e. Fast reactions have equilibrium constants > 1.
f. Increasing the concentration of a reactant always increases the rate of a reaction.
Draw the structure for the transition state in each reaction.
a.
b.
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