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Question: Classify the conversion of A to B as a substitution, elimination, or addition. B can be converted to the female sex hormone estrone in two steps.

Short Answer

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Answer

The conversion of A to B can be classified as an addition reaction.

Step by step solution

01

Step-by-Step SolutionStep 1: Substitution reactions

The chemical reactions that involve the replacement of an atom or group by another are referred to as substitution reactions.

02

Addition and elimination reactions

The reactions that involve the addition of atoms or groups to one another are termed addition reactions and the ones that involve the loss of atoms or molecules from a compound are termed elimination reactions.

03

Identifying the type of reaction

The conversion of A to B involves the addition of chlorine (Cl) and hydroxyl (OH) groups to the pi bond present in the five-membered ring.

Since the reaction involves the addition of two groups it can be classified as an addition reaction.

Reaction representing the addition of atoms to the pi bond

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Most popular questions from this chapter

What carbon radical is formed by homolysis of theC-Ha bond in propylbenzene? Draw all reasonable resonance structures for this radical.

What carbon radical is formed by homolysis of therole="math" localid="1648540916945" C-Hbbond in propylbenzene? Draw all reasonable resonance structures for this radical.

The bond dissociation energy of one of the C-H bonds is considerably less than the bond dissociation energy of the other. Which C-H bond is weaker? Offer an explanation.

Draw an energy diagram for each reaction. Label the axes, the starting material, product, transition state, ฮ”Hยฐ, and Ea.

a.a concertedwith ฮ”Hยฐ=-80kJ/moland Ea=16kJ/mol.

b. a two-step reaction, Aโ†’Bโ†’C, in which the relative energy of the compounds is A<C<B, and the step Aโ†’Bis rate-determining.

Consider the following energy diagram

  1. How many steps are involved in this reaction?
  2. Label โˆ†Hยฐand Ea for each step, and labelโˆ†Hยฐoverall .
  3. Label each transition state.
  4. Which point on the graph corresponds to a reactive intermediate?
  5. Which step is rate-determining?
  6. Is the overall reaction endothermic or exothermic?

The conversion of acetyl chloride to methyl acetate occurs via the following two-step mechanism:

a. Add curved arrows to show the movement of the electrons in each step.

b. Write the rate equation for this reaction, assuming the first step is rate-determining.

c. If the concentration of were increased 10 times, what would happen to the rate of the reaction?

d. If the concentrations of both and were increased 10 times, what would happen to the rate of the reaction?

e. Classify the conversion of acetyl chloride to methyl acetate as an addition, elimination, or substitution.

Classify each transformation as substitution, elimination, or addition.

a.

b.

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